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dc.contributor.author | Sáez-Pardo, Fermín![]() |
es_ES |
dc.contributor.author | Giner-Sanz, Juan José![]() |
es_ES |
dc.contributor.author | García Gabaldón, Montserrat![]() |
es_ES |
dc.contributor.author | Pérez-Herranz, Valentín![]() |
es_ES |
dc.date.accessioned | 2025-02-26T19:09:38Z | |
dc.date.available | 2025-02-26T19:09:38Z | |
dc.date.issued | 2024-10 | es_ES |
dc.identifier.issn | 0263-8762 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/214862 | |
dc.description.abstract | [EN] The severe consequences of thermal runaways, make process optimization of paramount importance for free radical polymerization reactors, in order to maximize in an integrated way their safety and productivity. Generally, this optimization is performed by simulation, for the sake of safety and cost. Today, the literature contains several models of free radical polymerization reactors in general; and methyl methacrylate (MMA) polymerization reactors, in particular. Although, MMA polymerization is commonly performed in semi-batch reactors at industrial level, most of the available models focus on batch reactors; while, the semi-batch reactor models are much scarcer. In this work, a model of a MMA solution polymerization batch reactor was modified in order to generalize it to semi-batch operation. The developed semi-batch model was used here for studying the effect of different operation conditions (feeding flow rate, initiator load, monomer initial load, and reactor temperature) on the quality characteristics of the produced polymer and on the safety and productivity of the polymerization reactor. The developed model can be used to optimize the operation conditions of a semibatch reactor so that the final product quality meets the application requirements, while maintaining the reactor within its safe-operation envelope, and maximizing its productivity. | es_ES |
dc.description.sponsorship | F.S.P. acknowledges the support of Universitat Politecnica de Valencia through a predoctoral fellowship (PAID-01-22) . J.J.G.S. is very grateful to the Ministerio de Ciencia e Innovacion, to the Next Generation EU, and to the Agencia Estatal de Investigacion, for their support by a Juan de la Cierva-Incorporacio n fellowship IJC2020-044087-I funded by MCIN/AEI/10.13039/501100011033 and by the European Union NextGenerationEU/PRTR. Funding for open access was provided by CRUE-Universitat Politecnica de Valencia. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation.ispartof | Chemical Engineering Research and Design | es_ES |
dc.rights | Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) | es_ES |
dc.subject | Polymerization reactor modelling | es_ES |
dc.subject | Polymethyl methacrylate | es_ES |
dc.subject | Semi-batch operation | es_ES |
dc.subject | Simulation | es_ES |
dc.subject | Solution polymerization | es_ES |
dc.subject.classification | INGENIERIA QUIMICA | es_ES |
dc.title | Modeling of a solution polymerization reactor operating in semi-batch mode for polymethyl methacrylate production | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1016/j.cherd.2024.08.024 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINISTERIO DE EDUCACION //IJC2020-044087-I//FALTA/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/UPV//PAID-01-22/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials | es_ES |
dc.description.bibliographicCitation | Sáez-Pardo, F.; Giner-Sanz, JJ.; García Gabaldón, M.; Pérez-Herranz, V. (2024). Modeling of a solution polymerization reactor operating in semi-batch mode for polymethyl methacrylate production. Chemical Engineering Research and Design. 210:230-246. https://doi.org/10.1016/j.cherd.2024.08.024 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1016/j.cherd.2024.08.024 | es_ES |
dc.description.upvformatpinicio | 230 | es_ES |
dc.description.upvformatpfin | 246 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 210 | es_ES |
dc.relation.pasarela | S\525100 | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.contributor.funder | MINISTERIO DE EDUCACION | es_ES |
dc.contributor.funder | Universitat Politècnica de València | es_ES |
upv.costeAPC | 3190 | es_ES |