Thermo-Compressed Films of Poly(butylene succinate) Reinforced with Cellulose Fibers Obtained from Rice Straw by Green Extraction Methods
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| dc.contributor.author | Olivas-Alonso, Carmen
|
es_ES |
| dc.contributor.author | Vieira-De Freitas, Pedro Augusto
|
es_ES |
| dc.contributor.author | Torres-Giner, S.
|
es_ES |
| dc.contributor.author | Chiralt, Amparo
|
es_ES |
| dc.date.accessioned | 2025-02-26T19:09:52Z | |
| dc.date.available | 2025-02-26T19:09:52Z | |
| dc.date.issued | 2024-10 | es_ES |
| dc.identifier.issn | 1438-7492 | es_ES |
| dc.identifier.uri | http://hdl.handle.net/10251/214873 | |
| dc.description.abstract | [EN] In this study, two green extraction methods are explored to valorize rice straw into cellulose fibers (CFs), namely subcritical water extraction (SWE) and combined ultrasound-heating treatment (USHT). The resultant fibers are, thereafter, successfully pretreated with (3-glycidyloxypropyl) trimethoxysilane (GPS) and incorporated at 3% wt into poly(butylene succinate) (PBS) by melt-mixing. The green composites are shaped into films by thermo-compression and characterized in terms of their performance for food packaging applications. The chemical analysis of the fibers reveals that SWE is more effective to selectively remove hemicelluloses than USHT, whereas silanization promotes the removal of lignin in both fiber types. Fiber incorporation, more notably in the case of the silanized fibers, restricts the movement of the PBS chains, indicating good interaction with the biopolyester matrix. In particular, CFs act as antinucleating agents in PBS, delaying both glass transition and crystallization from the melt phenomena and hindering crystal formation. Furthermore, the fibers mechanically reinforce and improve the oxygen barrier of the PBS films. The highest barrier enhancement is obtained for the thermo-compressed composite film with silanized fibers obtained by SWE, yielding a decrease of nearly 20% in the permeability to oxygen versus the unfilled PBS film.; Valorization of rice straw by green extraction methods, namely subcritical water extraction and combined ultrasound-heating treatment, leads to cellulose fibers. These fibers can be silanized and thereafter incorporated into poly(butylene succinate) by melt-mixing. The resultant green composites can be shaped by thermo-compression into films with improved rigidity and enhanced oxygen barrier, being of interest in food packaging applications. image | es_ES |
| dc.description.sponsorship | This research was funded by the Spanish Ministry of Science and Innovation (MICI), Grant No. PID2021-128749OB-C33, and Generalitat Valenciana (GVA), Grant Nos. AGROALNEXT/2022/026 and CIPROM/2021/071. Sergio Torres-Giner also acknowledged the financial support received during his Ramon y Cajal contract (RYC2019-027784-I) and Carmen Olivas-Alonso during her PhD scholarship (No. CIACIF/2021/422). | es_ES |
| dc.language | Inglés | es_ES |
| dc.publisher | John Wiley & Sons | es_ES |
| dc.relation.ispartof | Macromolecular Materials and Engineering | es_ES |
| dc.rights | Reconocimiento (by) | es_ES |
| dc.subject | Green composites | es_ES |
| dc.subject | Green extraction methods | es_ES |
| dc.subject | Renewable succinic acid derived polyesters | es_ES |
| dc.subject | Sustainable materials | es_ES |
| dc.subject | Waste valorization | es_ES |
| dc.subject.classification | TECNOLOGIA DE ALIMENTOS | es_ES |
| dc.title | Thermo-Compressed Films of Poly(butylene succinate) Reinforced with Cellulose Fibers Obtained from Rice Straw by Green Extraction Methods | es_ES |
| dc.type | Artículo | es_ES |
| dc.identifier.doi | 10.1002/mame.202400094 | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-128749OB-C33/ES/SINTESIS DE POLIMEROS BIODEGRADABLES BASADOS EN ACIDO SUCCINICO RENOVABLE CON PROPIEDADES DISEÑADAS A MEDIDA PARA EL ENVASADO SOSTENIBLE DE ALIMENTOS/ | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/GVA//CIPROM%2F2021%2F071/ES/Valorisation of agri-food waste to obtain biodegradable materials for active food pakaging/ | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/GVA//AGROALNEXT%2F2022%2F026/ES/Aprovechamiento integral de residuos agroalimentarios y su aplicación en el desarrollo de envases biodegradables activos para alimentos./ | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/GVA//CIACIF%2F2021%2F422/ES/VALORIZACIÓN DE RESIDUOS AGROALIMENTARIOS PARA EL DESARROLLO DE MATERIALES POLIMÉRICOS FUNCIONALES EN EL MARCO DE LA BIOECONOMÍA CIRCULAR/ | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Ayudas Ramón y Cajal Convocatoria 2019/RYC-2019-027784-I/ES/Novel Processes and Materials for Food Preservation in the frame of the Circular Bioeconomy | es_ES |
| dc.rights.accessRights | Abierto | es_ES |
| dc.contributor.affiliation | Universitat Politècnica de València. Escuela Técnica Superior de Ingeniería Agronómica y del Medio Natural - Escola Tècnica Superior d'Enginyeria Agronòmica i del Medi Natural | es_ES |
| dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario de Ingeniería de Alimentos para el Desarrollo - Institut Universitari d'Enginyeria d'Aliments per al Desenvolupament | es_ES |
| dc.description.bibliographicCitation | Olivas-Alonso, C.; Vieira-De Freitas, PA.; Torres-Giner, S.; Chiralt, A. (2024). Thermo-Compressed Films of Poly(butylene succinate) Reinforced with Cellulose Fibers Obtained from Rice Straw by Green Extraction Methods. Macromolecular Materials and Engineering. 309(10). https://doi.org/10.1002/mame.202400094 | es_ES |
| dc.description.accrualMethod | S | es_ES |
| dc.relation.publisherversion | https://doi.org/10.1002/mame.202400094 | es_ES |
| dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
| dc.description.volume | 309 | es_ES |
| dc.description.issue | 10 | es_ES |
| dc.relation.pasarela | S\525894 | es_ES |
| dc.contributor.funder | GENERALITAT VALENCIANA | es_ES |
| dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
| dc.contributor.funder | Universitat Politècnica de València | es_ES |
| dc.subject.ods | 02.- Poner fin al hambre, conseguir la seguridad alimentaria y una mejor nutrición, y promover la agricultura sostenible | es_ES |
| dc.subject.ods | 03.- Garantizar una vida saludable y promover el bienestar para todos y todas en todas las edades | es_ES |
| dc.subject.ods | 12.- Garantizar las pautas de consumo y de producción sostenibles | es_ES |
| dc.subject.ods | 14.- Conservar y utilizar de forma sostenible los océanos, mares y recursos marinos para lograr el desarrollo sostenible | es_ES |
| dc.subject.ods | 15.- Proteger, restaurar y promover la utilización sostenible de los ecosistemas terrestres, gestionar de manera sostenible los bosques, combatir la desertificación y detener y revertir la degradación de la tierra, y frenar la pérdida de diversidad biológica | es_ES |
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