Two-dimensional Co-based porphyrin metal-organic framework as heterogeneous catalyst for the aerobic oxidation of benzylic hydrocarbon
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| dc.contributor.author | Uscategui-Linares, Andrés Felipe
|
es_ES |
| dc.contributor.author | Santiago-Portillo, Andrea
|
es_ES |
| dc.contributor.author | Navalón Oltra, Sergio
|
es_ES |
| dc.contributor.author | Dhakshinamoorthy, Amarajothi
|
es_ES |
| dc.contributor.author | Albero-Sancho, Josep
|
es_ES |
| dc.contributor.author | Parvulescu, Vasile
|
es_ES |
| dc.contributor.author | García Gómez, Hermenegildo
|
es_ES |
| dc.date.accessioned | 2025-02-27T19:03:01Z | |
| dc.date.available | 2025-02-27T19:03:01Z | |
| dc.date.issued | 2024-07-15 | es_ES |
| dc.identifier.issn | 2468-8231 | es_ES |
| dc.identifier.uri | http://hdl.handle.net/10251/214921 | |
| dc.description.abstract | [EN] The development of heterogeneous catalysts for hydrocarbon oxidation by molecular oxygen as oxidant is an area of increasing interest from academia and chemical industry points of views. Herein, the catalytic activity of two-dimensional (2D) porphyrin metal -organic frameworks (MOFs) constituted by Co 2 + , Cu 2 + or Mn 3 + as transition metal ions coordinated to tetra(4-carboxyphenyl)porphyrin (TCPP) organic ligand as heterogeneous catalysts for the aerobic oxidation of benzylic hydrocarbon oxidation is reported. Selective radical quenching experiments and in -situ Raman measurements reveal the formation of superoxide/hydroperoxide and hydroxyl radicals during the catalytic reaction using Co-CoTCPP. | es_ES |
| dc.description.sponsorship | Financial support the Spanish Ministry of Science and Innovation (Severo Ochoa CEX2021-1230-S financed support by MCIN/AEI/10.13039/501100011033) , and Generalitat Valenciana (Prometeu 2021-038 and MFA-2022-023 financed by European Union-Next Generation EU, through the Conselleria de Innovacion, Universidades, Ciencia y Sociedad Digital) are gratefully acknowledged. J.A. thanks the Spanish Ministry of Science and Innovation for a Ramon y Cajal research associate contract (RYC2021-031006-I financed support by MCIN/AEI/10.13039/501100011033 and by European Union/NextGenerationEU/PRTR) . S.N. thanks the support of grant PID2021-123856OBI00 funded by MICIU/AEI/10.13039/501100011033 and by ERDF A way of making Europe. A.D. is beneficiary of a grant Maria Zambrano in Universitat Politecnica de Valencia within the framework of the grants for the retraining in the Spanish university system (Spanish Ministry of Universities, financed by the European Union, NextGeneration EU) .r (Severo Ochoa CEX2021-1230-S financed support by MCIN/AEI/10.13039/501100011033) , and Generalitat Valenciana (Prometeu 2021-038 and MFA-2022-023 financed by European Union-Next Gen-eration EU, through the Conselleria de Innovaci on, Universidades, Ciencia y Sociedad Digital) are gratefully acknowledged. J.A. thanks the Spanish Ministry of Science and Innovation for a Ramon y Cajal research associate contract (RYC2021-031006-I financed support by MCIN/AEI/10.13039/501100011033 and by European Union/NextGenerationEU/PRTR) . S.N. thanks the support of grant PID2021-123856OBI00 funded by MICIU/AEI/10.13039/501100011033 and by ERDF A way of making Europe. A.D. is beneficiary of a grant Maria Zambrano in Universitat Politecnica de Valencia within the framework of the grants for the retraining in the Spanish university system (Spanish Ministry of Uni-versities, financed by the European Union, NextGeneration EU) . | es_ES |
| dc.language | Inglés | es_ES |
| dc.publisher | Elsevier | es_ES |
| dc.relation.ispartof | Molecular Catalysis | es_ES |
| dc.rights | Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) | es_ES |
| dc.subject | Aerobic oxidation | es_ES |
| dc.subject | Indane | es_ES |
| dc.subject | Heterogeneous catalysis | es_ES |
| dc.subject | Metal organic frameworks | es_ES |
| dc.subject | Two-dimensional | es_ES |
| dc.subject.classification | QUIMICA ORGANICA | es_ES |
| dc.title | Two-dimensional Co-based porphyrin metal-organic framework as heterogeneous catalyst for the aerobic oxidation of benzylic hydrocarbon | es_ES |
| dc.type | Artículo | es_ES |
| dc.identifier.doi | 10.1016/j.mcat.2024.114288 | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-123856OB-I00/ES/FOTOCATALIZADORES MULTIFUNCIONALES BASADOS EN MATERIALES HIBRIDOS METAL-ORGANICO PARA LA REDUCCION SELECTIVA DE CO2 IMPULSADA POR LA ENERGIA SOLAR A COMBUSTIBLES Y PRODUCTOS/ | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/AGENCIA ESTATAL DE INVESTIGACION//CEX2021-001230-S//CENTRO DE EXCELENCIA SEVERO OCHO INSTITUTO DE TECNOLOGIA QUIMICA (ITQ)/ | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/GVA//PROMETEO%2F2021%2F038/ | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/GVA//MFA%2F2022%2F023/ | es_ES |
| dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//RYC2021-031006-I/ | es_ES |
| dc.rights.accessRights | Abierto | es_ES |
| dc.contributor.affiliation | Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials | es_ES |
| dc.description.bibliographicCitation | Uscategui-Linares, AF.; Santiago-Portillo, A.; Navalón Oltra, S.; Dhakshinamoorthy, A.; Albero-Sancho, J.; Parvulescu, V.; García Gómez, H. (2024). Two-dimensional Co-based porphyrin metal-organic framework as heterogeneous catalyst for the aerobic oxidation of benzylic hydrocarbon. Molecular Catalysis. 564. https://doi.org/10.1016/j.mcat.2024.114288 | es_ES |
| dc.description.accrualMethod | S | es_ES |
| dc.relation.publisherversion | https://doi.org/10.1016/j.mcat.2024.114288 | es_ES |
| dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
| dc.description.volume | 564 | es_ES |
| dc.relation.pasarela | S\523048 | es_ES |
| dc.contributor.funder | Generalitat Valenciana | es_ES |
| dc.contributor.funder | AGENCIA ESTATAL DE INVESTIGACION | es_ES |
| dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
| dc.contributor.funder | European Regional Development Fund | es_ES |
| dc.contributor.funder | Ministerio de Ciencia e Innovación | es_ES |
| dc.contributor.funder | Universitat Politècnica de València | es_ES |
| upv.costeAPC | 2840 | es_ES |
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