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Comprehensive modeling study analyzing the insights of the NO NO2 conversion process in current diesel engines

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dc.contributor.author Benajes Calvo, Jesus Vicente es_ES
dc.contributor.author López Sánchez, José Javier es_ES
dc.contributor.author Novella Rosa, Ricardo es_ES
dc.contributor.author Redón Lurbe, Pau es_ES
dc.date.accessioned 2015-05-04T12:04:05Z
dc.date.available 2015-05-04T12:04:05Z
dc.date.issued 2014-08
dc.identifier.issn 0196-8904
dc.identifier.uri http://hdl.handle.net/10251/49617
dc.description.abstract Multiple researches have focused on reducing the NOx emissions and the greatest results have been achieved when lowering the combustion temperature by employing massive exhaust gas recirculation rates (LTC). Despite this benefit, a substantial increase in the NO2 contribution to the NOx emissions has also been observed, which is the most harmful specie and is important for the design and positioning of the after-treatment devices. To understand how NO2 behaves and how it contributes to the total NOx (NO2/NOx), not only under LTC but also for CDC conditions, a stepwise computational research study was performed with Chemkin Pro software, due to the complexity of isolating the different phenomena studied, to analyze: (1) general equilibrium conditions and (2) the influence of typical diesel engine phenomena (combustion and cooling effects) under non-equilibrium conditions. The results obtained under equilibrium state confirm the theoretical guidelines established for the NO2 formation process. When considering a combustion process (HCCI-like mode), the previous results were corroborated as well as the fact that only poor or slow combustion processes are responsible for the NO2 formation. Additionally, it reflected a cyclic process between NO and NO2, or in other words, it is suffice to just concentrate on NO to be able to predict NO2. Finally, the results yield after analyzing some cooling effects, inherent to how diesel engines work (the expansion stroke, dilution of combustion products with the rest of in-cylinder charge and the one caused by wall impingement), reflect that: (1) the dilution effect explains the 10% of the NO2/NOx ratio under CDC conditions and (2) the coupling of the dilution with the expansion stroke cooling effects can explain the NO2 increase typical of LTC conditions. These results were also supported by some experiments performed in a single-cylinder diesel engine. Consequently, the cooling effect caused by dilution should be considered when modeling the NO2 formation just like the expansion stroke. es_ES
dc.description.sponsorship The authors would like to acknowledge the contribution of the Spanish Ministry of Economic and Competitively for the financial support of the present research study associate to the Projects TRA 2008-06448 (VELOSOOT) and TRA 2010-20271 (LOWTECOM). Additionally, special acknowledgement to Dr. L. Pickett which kindly shared a copy of the TSL model to perform the diesel spray simulations. en_EN
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Energy Conversion and Management es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Low temperature combustion es_ES
dc.subject Conventional diesel combustion es_ES
dc.subject NOx emission es_ES
dc.subject NO2 formation es_ES
dc.subject 0-D modeling es_ES
dc.subject Diesel engines es_ES
dc.subject.classification MAQUINAS Y MOTORES TERMICOS es_ES
dc.title Comprehensive modeling study analyzing the insights of the NO NO2 conversion process in current diesel engines es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.enconman.2014.04.073
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//TRA2010-20271/ES/COMBUSTION A BAJA TEMPERATURA EN MOTORES DIESEL PARA REDUCIR SIMULTANEAMENTE LAS EMISIONES DE NOX Y HUMOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//TRA2008-06448/ES/ESTUDIO DE COMPRENSION DE PROCESOS DE COMBUSTION DIESEL CON BAJA FORMACION DE HOLLIN/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario CMT-Motores Térmicos - Institut Universitari CMT-Motors Tèrmics es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Máquinas y Motores Térmicos - Departament de Màquines i Motors Tèrmics es_ES
dc.description.bibliographicCitation Benajes Calvo, JV.; López Sánchez, JJ.; Novella Rosa, R.; Redón Lurbe, P. (2014). Comprehensive modeling study analyzing the insights of the NO NO2 conversion process in current diesel engines. Energy Conversion and Management. 84:691-700. https://doi.org/10.1016/j.enconman.2014.04.073 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1016/j.enconman.2014.04.073 es_ES
dc.description.upvformatpinicio 691 es_ES
dc.description.upvformatpfin 700 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 84 es_ES
dc.relation.senia 267263
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES


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